As polyvinyl chloride (PVC) films are hard and brittle in a low-temperature environment, aliphatic dibasic acid ester plasticizers with different acid chain lengths were fabricated, i.e. di(2-ethylhexyl) adipate (DOA), di(2-ethylhexyl) sebacate (DOS) and dioctyl dodecanedioate (DOD), and their effects on the cold-resistant properties of PVC were investigated using experiments and molecular dynamics (MD) simulations. The brittleness temperature and tensile properties of plasticizers/PVC are negatively related to the acid chain length of the aliphatic dibasic acid esters. The brittleness temperatures of the three systems are all below –50 °C. In-situ low-temperature tensile tests and aging tests indicate that DOA/PVC exhibits the best cold resistance and stability. MD simulations further reveal that the best compatibility between DOA and PVC is attributed to its strong binding energy and weak hydrogen bonding interactions, while van der Waals forces are dominant in DOS/PVC and DOD/PVC. This study elucidates the structure-property relationship between aliphatic dibasic acid ester plasticizers and PVC from the perspective of molecular interactions, and provides insights into the design of cold-resistant PVC plasticizers.

Composite materials are of increasing interest in aircraft and spacecraft structures, and carbon fiber reinforced polymers (CFRP) have emerged as materials meeting quality standards for structural applications in the aircraft industry. Despite their high mechanical properties, CFRPs are associated with high production costs. Building on recent research by the authors, this paper investigates the use of ply-level hybridization to reduce manufacturing costs while maintaining the mechanical performance of the manufactured material. Focusing on the causes of nonlinear response under off-axis tensile loading, the paper involves cyclic load-unload (LU) tensile tests conducted at off-axis angles of 15°, 30°, and 45° to predict mechanical characteristics and damage evolution. Residual strains are directly extracted from load-unload stress-strain responses. Three distinct methods for estimating cycle modulus are employed and compared for damage variable formulation. The research findings reveal dependencies of both the damage variable and residual strains on the off-axis angle. Furthermore, the method used to assess the modulus during cycling loading significantly influences the damage variable estimation. Encouragingly, the hybrid laminates exhibit reduced internal damage and matrix plasticity compared to reference counterparts, indicating a positive effect on the mechanical performances of hybridized CFRPs in addition to the cost reduction.