We have discovered that water-insoluble proteins (IM) isolated from whole soy meal (WM) have the capacity to improve the thermal stability of polypropylene (PP) wood composites without negatively impacting mechanical properties. We compared an undiluted composite to composites diluted with 5% by weight of a 3/1 w/w mixture of stearic acid and paraffin wax (SA/wax), 5% by weight IM, 5% by weight WM, 5% by weight of a 50/50 w/w mixture of IM in combination with SA/wax, and 5% by weight WM in combination with SA/wax. Water contact angle (CA) measurements and Fourier transform infrared spectroscopy (FTIR) revealed a synergy between IM and SA/wax, resulting in enhanced surface hydro - phobicity. Thermogravimetric analysis (TGA) showed lower weight loss in composites made with IM up to the onset of the degradation of PP, and reduced rates of lignin degradation, independently of the presence of SA/wax. Dynamic mechanical analysis (DMA) revealed higher modulus and lower viscoelastic loss resulting from the removal of water-soluble soy components from WM. Total reflectance ultraviolet spectroscopy (UV) showed that IM absorbs UV radiation strongly in the UV-B and UV-C regions. Collectively, these findings suggest that IM has the potential to become a multi-purpose additive for use in PP wood composites.

Polymer composites are widely used in indoor and outdoor applications owing to their high strength-to-weight ratio, corrosion resistance, and design flexibility. However, exposure to environmental factors such as ultraviolet (UV) radiation, humidity, temperature fluctuations, and biological agents significantly affect their long-term durability and performance. In this review, we comprehensively examine the degradation mechanisms of polymer composites under both natural and accelerated weathering, with particular emphasis on degradation mechanisms, characterization techniques, and durability assessment. We critically discuss the fundamental degradation mechanisms, including photo-oxidation, hydrolysis, polymer chain scission, crosslinking and interfacial debonding. We also evaluated accelerated weathering techniques, conducted under standardized testing conditions, for their ability to simulate long-term outdoor exposure within significantly shorter timeframes, by controlling key environmental parameters such as UV radiation, humidity, and temperature. We also examine the influence of reinforcements, including natural fibres, synthetic fibres, and nanofillers, on the weathering resistance of polymer composites. Attention is given to natural fibre–reinforced composites because their inherent hydrophilicity promotes moisture absorption, accelerating degradation and weakening the fibre–matrix interface. Furthermore, we critically evaluate the effects of weathering on the mechanical properties, crystalline structure and barrier performance of polymer composite films, and discuss recent advances in enhancing weather resistance through hybridization, surface modification, and the incorporation of stabilizing additives. Finally, the review highlights the key challenges and future research directions for the development of durable, high-performance, and sustainable polymer composite systems for long-term outdoor applications.

This is an editorial article. It has no abstract.

In this study, we present an effective chemo-enzymatic method for synthesizing di- and tetra-carboxyl–functionalized poly(ethylene glycol)s (PEGs) using Candida antarctica lipase B (CALB). PEG-diacid was synthesized through CALB-catalyzed Michael addition of 3-mercaptopropionic acid (3-MPA) to PEG-diacrylate. We found that the reactions proceeded in a stepwise manner, first producing monoacid. The synthesis of diacid required additional fresh CALB and 3-MPA. The structure of the products was confirmed by 800 MHz ¹H NMR. PEG-tetraacid was synthesized in a single step via CALB-catalyzed Michael addition of acrylic acid to PEG-diamine. In both cases, the CALB-Catalyzed Michael addition reactions effectively produced carboxyl-functionalized PEGs.

This is an editorial article. It has no abstract.