Thermomechanical properties of the silanized-kenaf/polystyrene composites
Y. Xu, S. Kawata, K. Hosoi, T. Kawai, S. Kuroda
Vol. 3., No.10., Pages 657-664, 2009
DOI: 10.3144/expresspolymlett.2009.82
DOI: 10.3144/expresspolymlett.2009.82
GRAPHICAL ABSTRACT
ABSTRACT
In order to improve the poor interfacial adhesion of the kenaf fiber and polystyrene (PS) in their composite material, the surface of the kenaf fiber was modified using a synthesized polymeric coupling agent to promote adhesion with PS matrix. The dynamic thermo-mechanical properties of the composite composed of modified kenaf fiber and PS were also investigated. The polymeric coupling agent treatment of the kenaf fiber increased the fiber-matrix interaction through a condensation reaction between alkoxysilane and hydroxyl groups of kenaf cellulose. DMA (Dynamic Mechanical Thermal Analysis) results showed that the modified fiber composites have higher E′ and lower tanδ than those with untreated fiber indicating that a greater interfacial interaction between the matrix resin and the fiber. It was also found that the storage modulus increases in proportion with the Si/C ratio on the fiber surface.