Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
X. Q. Liu, W. Huang, Y. H. Jiang, J. Zhu, C. Z. Zhang
Vol. 6., No.4., Pages 293-298, 2012
DOI: 10.3144/expresspolymlett.2012.32
DOI: 10.3144/expresspolymlett.2012.32
Corresponding author: X. Q. Liu 
GRAPHICAL ABSTRACT
ABSTRACT
In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg) of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.
