Conductive polymer foams with carbon nanofillers – Modeling percolation behavior
O. Maxian, D. Pedrazzoli, I. Manas-Zloczower
Vol. 11., No.5., Pages 406-418, 2017
DOI: 10.3144/expresspolymlett.2017.39
DOI: 10.3144/expresspolymlett.2017.39
Corresponding author: D. Pedrazzoli 
GRAPHICAL ABSTRACT
ABSTRACT
A new numerical model considering nanofiller random distribution in a porous polymeric matrix was developed to predict electrical percolation behavior in systems incorporating 1D-carbon nanotubes (CNTs) and/or 2D-graphene nanoplatelets (GNPs). The numerical model applies to porous systems with closed-cell morphology. The percolation threshold was found to decrease with increasing porosity due to filler repositioning as a result of foaming. CNTs were more efficient in forming a percolative network than GNPs. High-aspect ratio (AR) and randomly oriented fillers were more prone to form a network. Reduced percolation values were determined for misaligned fillers as they connect better in a network compared to aligned ones. Hybrid CNT-GNP fillers show synergistic effects in forming electrically conductive networks by comparison with single fillers.
