This study investigates the structure–property relationships of multi-functional urethane acrylate resins designed as photoreactive binders for UV-curable nail coatings. Four systems were examined: a commercial resin urethane dimethacrylate (UDMA), a bio-based acrylated epoxidized soybean oil (AESO), and two newly synthesized bio-based urethane acrylates derived from 1,3-propanediol (PDO–UA) and eugenol (EUG–UA). Photopolymerization kinetics were analyzed by realtime FTIR, while the properties of the cured coatings were also determined. The mechanical and thermal behavior of selfsupporting polymer films was evaluated by tensile testing and DSC analysis. The UDMA network exhibited the highest crosslink density, reflected in its high modulus (≈0.5 GPa), tensile strength (≈15 MPa), and Tg (≈60°C), making it suitable for use as a top coat. AESO showed moderate stiffness and flexibility, whereas PDO–UA and EUG–UA formed soft, low-Tg (–12 and –17°C) and highly deformable networks typical of elastomeric materials. The combined mechanical and thermal results confirmed that crosslink density strongly governs coating performance and applicability. This study demonstrates that blending UDMA with bio-based oligomers enables the design of sustainable, UV-curable nail lacquers with an optimal balance of hardness, flexibility, and adhesion to the natural nail plate.

This study investigates the interaction between poly(butylene adipate-co-terephthalate) (PBAT) and amber powdered waste (AbW) from jewelry at different filler concentrations (0, 1, 2.5, and 5 wt%) obtained via melt mixing in a corotating twin screw extruder. The resulting materials were pelletized and processed using two techniques: 1) cast film extrusion and 2) injection molding. The shaped specimens exhibited excellent interfacial adhesion. Thermal behavior, as assessed by Vicat softening temperature (VST), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA), showed minimal variation among the composites. Despite similar melt flow rate (MFR) values among the samples, the incorporation of AbW affected the behavior of the polymer during cast film extrusion. Consequently, the composite films exhibited lower tensile mechanical parameters (tensile strength, Young’s modulus, stress and strain at break) compared to the neat PBAT film. In turn, the injection molded composites showed improved tensile, flexural, and impact parameters compared to their neat counterpart. Additionally, a slight decrease in water contact angle (WCA) suggested increased surface hydrophilicity of the extruded films. These findings demonstrate the potential of AbW as an additive for biopolymer composites with enhanced mechanical performance. The increased surface hydrophilicity is particularly relevant for applications targeting biocompatibility and biodegradability.

In recent decades, numerous efforts have been dedicated to the investigation of eco-friendly non-isocyanate polyurethanes (NIPUs) as alternatives to conventional polyurethanes (PUs). Since isocyanates are classified by the EU as hazardous and toxic compounds, NIPUs offer a promising route to mitigate isocyanate-related health risks as well as other environmental concerns associated with traditional PU synthesis. In the present study, we report the synthesis as well as the detailed structural and thermal characterization of a new series of fully biobased non-isocyanate polyurethanes (NIPUs) based on aliphatic dicarboxylic acids of different chain lengths. The NIPUs were prepared via a two-step polyaddition reaction involving glycerol carbonate and diamine. Their synthesis enables a sustainable pathway to tailor NIPUs’ physicochemical properties via diacid structure control. Studies of their structure, thermal behavior and trends, morphological, and hydrolytic findings confirmed strong diacid chain length dependence on glass transition temperature (T_g ~13, 0, ‒5 and –23 °C), molecular weight, surface wettability, and enzymatic degradability. Short-chain diacids yielded NIPUs with rapid hydrolytic degradation, while their longer-chain analogs were hydrophobic and thermally stable. Contact angle measurements (~75–85°) also confirm these trends. The tunable properties position these materials among strong candidates for biomedical applications.

This research presents an eco-friendly approach for extracting chitosan from shrimp shell waste through ultrasound-assisted extraction (UAE) to prepare biocompatible aerogel scaffolds for biomedical applications. The study investigates the influence of various ultrasonic treatment times (10, 20, 30, 40 min) on the yield and structural and physicochemical properties of the extracted chitosan via characterization using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). Among the tested conditions, the 30 min UAE-treated chitosan aerogels showed optimal porosity and structural integrity. Biocompatibility of the aerogels was evaluated, and the results confirmed their non-cytotoxic nature. The bioactivity of the chitosan aerogels was evaluated in terms of their in vitro wound closure ability and antibacterial properties. The aerogels demonstrated a wound closure rate of around 51% after 72 h, significantly higher than the untreated control (37%). In addition, they exhibited clear antibacterial activity against Escherichia coli and Staphylococcus aureus. This sustainable extraction and fabrication method not only adds value to marine waste but also produces functional biomaterials with potential applications in wound healing, tissue engineering, and regenerative medicine, supporting global efforts toward sustainability and circular bioeconomy.

The growing focus on sustainability, eco-friendly technologies, decarbonization, and reducing carbon footprints shapes current industry challenges. This article reviews the potential of cinnamon as a bio-additive for polymer stabilization in packaging. Samples were prepared from ethylene-norbornene copolymer (Topas), a cyclic olefin copolymer known for purity, transparency, and low gas permeability, and poly(lactic acid) (PLA), a bio-based alternative to petroleum plastics. Cinnamon powder was added in 0.5, 1.0, and 1.5 wt%. After solar and thermo-oxidative aging, hydrophobicity, chemical composition, mechanical, and color properties were analyzed. Results showed higher hydrophobicity and resistance to hydrolytic degradation due to reduced water penetration. PLA, normally brittle, became more flexible, with 0.5 wt% cinnamon showing optimal performance after 100 h of solar aging, similar to Topas composites. Overall, PLA and cyclic olefin copolymer (COC) films with cinnamon improved durability, extended food shelf life, and acted as natural color indicators of material aging.