We have discovered that water-insoluble proteins (IM) isolated from whole soy meal (WM) have the capacity to improve the thermal stability of polypropylene (PP) wood composites without negatively impacting mechanical properties. We compared an undiluted composite to composites diluted with 5% by weight of a 3/1 w/w mixture of stearic acid and paraffin wax (SA/wax), 5% by weight IM, 5% by weight WM, 5% by weight of a 50/50 w/w mixture of IM in combination with SA/wax, and 5% by weight WM in combination with SA/wax. Water contact angle (CA) measurements and Fourier transform infrared spectroscopy (FTIR) revealed a synergy between IM and SA/wax, resulting in enhanced surface hydro - phobicity. Thermogravimetric analysis (TGA) showed lower weight loss in composites made with IM up to the onset of the degradation of PP, and reduced rates of lignin degradation, independently of the presence of SA/wax. Dynamic mechanical analysis (DMA) revealed higher modulus and lower viscoelastic loss resulting from the removal of water-soluble soy components from WM. Total reflectance ultraviolet spectroscopy (UV) showed that IM absorbs UV radiation strongly in the UV-B and UV-C regions. Collectively, these findings suggest that IM has the potential to become a multi-purpose additive for use in PP wood composites.

An excessive intake of high-fat foods may pose a threat to human health. Oleogelation provides a promising strategy to reduce trans and saturated fatty acids in solid fats. Compared with small-molecule gelators, macromolecular gelators, particularly proteins, polysaccharides and their complexes are more suitable for this purpose. In this review, we systematically discuss the development potential of biopolymer-based oleogels. First, we elaborate the application of proteins, polysaccharides and their complexes as gelling agents. Second, despite the inherent hydrophilicity of these biopolymers, significant progress has been made in developing various preparation approaches, ranging from indirect templating strategies to direct dispersion methods. Third, we briefly discuss the underlying structuring mechanisms of these oleogels. Subsequently, we review their applications as fat replacers in specific food products. Finally, we present the conclusions and remaining challenges in this field. We aim to provide valuable insights into the utilization of biopolymer-based oleogels in the food industry.

Freeze-thaw (F-T) poly(vinyl alcohol) (PVA) as a soft network and ionic-crosslinked sodium carboxymethyl cellulose (CMC) as a hard network were applied to fabricate a double network (DN) gel using a one-step process. Mechanical properties of the DN gel using a high degree of hydrolysis PVA (PVA-CMC of 60-1) were significantly improved compared to that of a single network gel of PVA. The tensile strength of ~0.55 MPa and elongation at break of 179% could be achieved. The mechanical properties of PVA-poly(acrylic acid) DN gel were lower than that of PVA-CMC samples. Fourier-transformed infrared (FTIR) spectroscopy results showed less compatibility between polyacrylic acid (PAA) and PVA compared to that of CMC. The solution made from the lower hydrolysis degree PVA (PVA1788) could form a strong gel after being treated with NaOH 1 M. The FTIR result showed the disappearance of acetate groups. A large melting peak in differential scanning calorimetry (DSC) results showed high crystallinity of the hydrolyzed-PVA1788. The effect of various multivalent cations on the mechanical properties of PVA1788-CMC DN gel was performed. The properties of the samples followed the order: Fe³⁺<Co²⁺<Ni²⁺<Cu²⁺<Zn²⁺<Ca²⁺~Ba²⁺<Al³⁺. The tensile strength of DN gel fabricated using AlCl3 solution could reach 0.87 MPa, and the elongation at break was 330%.

Biodegradable biopolymers like polyhydroxybutyrate (PHB) hold promise for sustainable packaging, but their inherent degradability reduces material stability. Synthetic stabilizers, though effective, raise environmental and potential toxicity concerns. This study explores a multifunctional natural anti-aging agent: a hemp extract rich in cannabidiol (CBD) and cannabichromene (CBC). PHB composites with varying hemp extract concentrations were prepared and subjected to thermooxidative and weathering aging. Characterization employed FTIR-ATR, carbonyl index, and spectrophotometry. Static mechanical properties, DSC, and surface free energy (SFE) were also assessed. Notably, the hemp extract exhibited stability under ambient conditions but showed migration with time and aging. The results suggest a plasticizing effect on PHB and highlight the contrasting roles of the extract: inhibiting thermooxidative aging while potentially accelerating aging under atmospheric conditions. This opens avenues for tailoring material durability, further evaluated by life cycle analysis (LCA). This work represents one of the first investigations into hemp extract as an anti-aging agent for eco-friendly polymers, expanding the knowledge base of natural multifunctional additives.

Seaweed from macroalgae and cellulose from nonwood materials have gained attention in various fields. This study explores how seaweed and cellulose nanofibers (CNF) interact to form 3D networks in composite bioaerogels. The ratio of CNF and seaweed was varied to see how it affects the aerogel’s inside and its properties. The observations show that the biocomposite aerogel is more rigid and shrinks less than using a single biopolymer. The CNF aerogel has a fine, thin network structure, and the seaweed aerogel has a thin sheet structure. The biocomposite aerogel combines both a fine network and a thin sheet structure. The composite aerogel’s mechanical properties are significantly influenced by seaweed composition. The introduction of CNF increases elasticity, while seaweed enhances firmness. Generated computer modelling revealed that the abundant hydroxyl groups in CNF facilitated the formation of intermolecular bonds with seaweed. The bonding led to increased adhesion and entanglement between biopolymers, consequently enhancing elasticity and establishing a stable intermolecular interaction. The 3D X-ray imaging model shows that the skeletal framework primarily consists of seaweed biopolymer, with CNF serving to reinforce this structure thus enhancing the mechanical properties and robustness of the composite bioaerogels.